Complexities in the Molecular Spin Crossover Transition
نویسندگان
چکیده
منابع مشابه
Structure:function relationships in molecular spin-crossover complexes.
Spin-crossover compounds are becoming increasingly popular for device and sensor applications, and in soft materials, that make use of their switchable colour, paramagnetism and conductivity. The de novo design of new solid spin-crossover compounds with pre-defined switching properties is desirable for application purposes. This challenging problem of crystal engineering requires an understandi...
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Z. Wu (吴忠庆 ,1 J. F. Justo,1,2 C. R. S. da Silva,3 S. de Gironcoli,4,5 and R. M. Wentzcovitch1,3 1Department of Chemical Engineering and Materials Science, University of Minnesota, Minneapolis, Minnesota 55455, USA 2Escola Politécnica, Universidade de São Paulo, CP 61548, CEP 05424-970 São Paulo, SP, Brazil 3Minnesota Supercomputing Institute, University of Minnesota, Minneapolis, Minnesota 5545...
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Three new compounds have been synthesized and characterized with Fe(II), Co(II) and Mn(II), the polynitrile anionic ligand 1,1,3,3-tetracyano-2-(3-hydroxypropoxy)-propenide (tcnopr3OH ́) and the co-ligand 4,41-bipyridine (4,41-bpy). The Fe(II) compound, formulated as [FeII(tcnoprOH)2(H2O)2(4,41-bpy)2] (1), contains monomeric complexes where the Fe(II) ion is coordinated to two trans polynitrile ...
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ژورنال
عنوان ژورنال: The Journal of Physical Chemistry C
سال: 2015
ISSN: 1932-7447,1932-7455
DOI: 10.1021/acs.jpcc.5b02220